• Motivational
  • Board Exams
  • Exam Prep Tips
  • Science & Tech
Friday, January 27, 2023
  • Login
Aakash BYJU'S Blog
  • Aakash Home
  • MEDICAL
  • ENGINEERING
  • FOUNDATIONS
  • TOPPERS SPEAK
  • Exam
    • NEET
      • NEET 2023 Eligibility Criteria
      • NEET 2023 Dates
      • NEET 2023 Exam Pattern
      • NEET 2023 Syllabus
      • NEET 2023 Application
      • NEET 2023 Admit Card
      • NEET UG 2023 Result
      • NEET 2023 Cut Off
      • NEET 2023 FAQ
    • JEE Main
      • JEE Main 2023 Eligibility Criteria
      • JEE Main 2023 Dates
      • JEE Main 2023 Exam Pattern
      • JEE Main 2023 Syllabus
      • JEE Main 2023 Application
      • JEE Main 2023 Admit Card
      • JEE Main 2023 Counselling
    • JEE Advanced
      • JEE Advanced 2023 Eligibility Criteria
      • JEE Advanced 2023 Dates
      • JEE Advanced 2023 Application
      • JEE Advanced 2023 Syllabus
      • JEE Advanced 2023 Maths Syllabus
      • JEE Advanced 2023 Physics Syllabus
      • JEE Advanced 2023 Chemistry Syllabus
  • NCERT Solutions
  • NEET PG
    • INI CET
No Result
View All Result
  • Aakash Home
  • MEDICAL
  • ENGINEERING
  • FOUNDATIONS
  • TOPPERS SPEAK
  • Exam
    • NEET
      • NEET 2023 Eligibility Criteria
      • NEET 2023 Dates
      • NEET 2023 Exam Pattern
      • NEET 2023 Syllabus
      • NEET 2023 Application
      • NEET 2023 Admit Card
      • NEET UG 2023 Result
      • NEET 2023 Cut Off
      • NEET 2023 FAQ
    • JEE Main
      • JEE Main 2023 Eligibility Criteria
      • JEE Main 2023 Dates
      • JEE Main 2023 Exam Pattern
      • JEE Main 2023 Syllabus
      • JEE Main 2023 Application
      • JEE Main 2023 Admit Card
      • JEE Main 2023 Counselling
    • JEE Advanced
      • JEE Advanced 2023 Eligibility Criteria
      • JEE Advanced 2023 Dates
      • JEE Advanced 2023 Application
      • JEE Advanced 2023 Syllabus
      • JEE Advanced 2023 Maths Syllabus
      • JEE Advanced 2023 Physics Syllabus
      • JEE Advanced 2023 Chemistry Syllabus
  • NCERT Solutions
  • NEET PG
    • INI CET
No Result
View All Result
Aakash Institute Logo
No Result
View All Result

Home » Aakash Coaching » What is Resonance? CBSE Class 11 Chemistry note by experts

    Talk to our expert



    Resend OTP

    By submitting up, I agree to receive all the Whatsapp communication on my registered number and Aakash terms and conditions and privacy policy

    What is Resonance? CBSE Class 11 Chemistry note by experts

    Are you a student of Class 11 Chemistry? Here are some expert tips on the chapter Resonance

    by Team @Aakash
    Apr 14, 2022, 11:30 AM IST
    in Aakash Coaching
    0
    Class 12 Chemistry: Important Topics Chapter Wise for CBSE Term 2 Exam 2022

    Class 12 Chemistry: Important Topics Chapter Wise for CBSE Term 2 Exam 2022

    0
    SHARES
    923
    VIEWS
    Share on FacebookShare on Twitter

    Resonance, also known as mesomerism in molecular biology, is a process of representing togetherness in specific molecules and ions by combining several contributory structures, also renowned as resonance structures or canonical structures, into the resonance hybrid in valence bond theory. It is especially useful for describing delocalized electrons within particles or polyatomic ions where a solitary Lewis structure cannot express the connectivity. Resonance is a process of representing interlayer electrons within particles or polyatomic ions in which the connections cannot be expressed using a single Lewis formula. Several resonance structures represent a molecule or ion with such unpaired electrons. The Lewis’ nuclear skeleton Only the electron locations differ in the structure of these ring structures. 

    Table of Contents
    Resonance Structure
    Resonance Energy
    Effect of Resonance
    Positive Effect of Resonance
    Negative Effect of Resonance
    Resonance Hybrid
    Rules of Resonance
    Stable Resonance Structure
    Conclusion 
    FAQs

    Resonance Structure

    Resonance Structures are collections of Lewis structures that define electron delocalization in a polyatomic ion or molecule. Because of the presence of partial charges and partial bonds in a molecule, a separate Lewis structure fails to describe its bonding in many cases. Resonance structures are being used to characterise chemical bonding in such cases. Structures of resonance are described as the variation in bond energy between the actual bond energy and the energy of the most steady resonating structures. Resonance is the average of a molecule’s bond characteristics.

    Because the power of the resonant frequency hybrid is much less than the vitality of any canonical form, resonance stabilises the molecule. 

    Three C-C connections and 3 C=C bonds are present in this structure.

    The length of a carbon-carbon double bond is 1.34 A.

    The length of a single carbon-carbon bond is 1.54A.

    Resonance Energy

    The difference in energy between a compound’s greatest stable contributing structure and its resonance hybrid is called resonant frequency energy or resonance stabilisation energy. The Resonance Energy needed to transform the interlayer structure into a stable making a contribution structure is referred to as resonance energy. Whenever the electromotive force is spread across more than one atom, this is called delocalization. 

    Effect of Resonance

    The resonance Effect describes the polarity stimulated in a particle by the reaction of a pair of electrons and a pi bond. It is also produced by the reaction of two pi bonds in adjacent atoms. In its most basic form, Resonance refers to particles with numerous Lewis structures. In chemistry, resonance assists in understanding the consistency of a compound and its energy states. Polarity is created in a chemical compound even by interactions between two -bonds or a -bond and a pair of electrons on an adjacent atom. There are two kinds of resonance effects known as R and M effects.

    Positive Effect of Resonance

    The positive resonance effect occurs when the groups delocalize and start releasing electrons to other molecules. The groups are typically signified by +R and +M – the single-molecule electron density increases during this process. Examples of  Positive Resonance effects include phenomena in terms -OR, -SH, and -SR. 

    Negative Effect of Resonance

    When groups delocalize, they withdraw electrons from other molecules, resulting in a negative resonance effect. The groups are typically denoted by the suffixes -R or -M. The molecular electronic structure is said to decrease during this process. For example, NO2, C=O,−COOH,−C≡N. The electrons are transferred towards the atom, or functional groups are attached to the conjugated system in this effect. e.g. nitrobenzene. In the Negative Resonance effect, the electrons are transferred to the conjugated system’s atom or a substituent group. More than each appropriate Lewis structure could be used to portray the chemical compound.

    All resonant frequency structures should vary only in electron positions, not in particle or nuclei positions.

    Resonance Hybrid

    A resonance Hybrid is a chemical, molecule, atom, or radical which exhibits resonance. It has a structure written as the average of 2 or even more systemic formulas separated by the double arrow. Specific Lewis structures are referred to as resonance structures. The actual electronic properties are termed a resonance hybrid of individual resonance forms. The double arrow among Lewis structures denotes resonance forms. 

    Rules of Resonance

    Molecules are sometimes symbolised by much more than one Lewis structure, with the only difference being the place of the pi electrons. Electrons in sigma bonds have a fixed structure; this is known as localised electrons, but they never move. On the other side, Pi electrons are referred to as delocalized since they can be easily transported around. Whenever these Lewis graphs are combined, they are referred to as resonance structures, resonance contributors, or resonance canonicals. The actual molecule possesses characteristics of each component and can be symbolised as a resonant hybrid. Resonance Hybrids are a much more accurate way of thinking about resonance structures because they resemble the structure in nature. 

    Rule 1- Understand “the natural state of each atom. Individuals must be familiar with the general appearance of each atom they are dealing with in an inert state. This will assist in building the Lewis Dot framework on which structures will be based. Halogens and hydrogens are always terminal, meaning they are at the end of the molecule and have only one bond; therefore, they will not participate. 

    Rule 2- The positions of the atoms will not change. Once defined that an atom is formed by a bond to some other atom, the order of the atoms in a resonance structure will not change. If they change, the structure would no longer be a resonance structure but a constitutional isomer or tautomer.

    Rule 3- When two or more structures can be drawn, the one with the least amount of total charges is by far the most stable. Numerous charges on atomic nuclei could exist, but this is generally seen when an acid and a base are present on the same particle.  

    Rule 4- The distance of such a bond between the two atoms is affected by resonance. It makes much more sense when viewed through the lens of resonance hybrids. Resonance, in essence, could even create two bond lengths equitable. 

    Stable Resonance Structure

    In a Stable Resonance Structure, the distance of such a bond between the two atoms is affected by resonance. It makes much more sense when viewed through the lens of resonance hybrids. Resonance, in essence, could even create two bond lengths equitable. Since resonance enables dissociation, which lowers a particle’s overall energy because its charged particles occupy a higher quantity, particles that encounter resonance are much more steady than those that do not. These molecules are known as resonance stabilised molecules. 

    Rule 1- Any single structure is much less stable than the resonance hybrid.

    Rule 2- Structures without charges are more stable than structures without charges.

    Rule 3- Structures with fewer formal charges are much more secure than those with more.

    Rule 4- The negative charge will be positioned on one of the most electronegative atoms in the most stable structure.

    Rule 5- The positive charge will be placed on the least ionic bond in the most stable structure.

    Conclusion

    Resonance Theory is the concept of resonance in inorganic chemistry that was largely developed between 1927 and 1933 on the basic principle of Heisenberg’s subatomic theory of the reactive species and triple bond states of the helium nucleus named quantum-mechanical resonance. Resonance method. To describe the configuration of a species, such as a nitrate ion or benzoic acid, for which no Lewis diagram is consistent with the observed properties. The major benefit of resonance theory would be that, despite being based on mathematically rigorous analysis, it can be successfully applied with no math. The direction generated in a molecule by the engagement of a pair of electrons and a pi bond, or even by the interactions between two pi covalent bond adjacent atoms, is known as the Resonance Effect.

    The resonant frequency effect can be observed in molecules with conjugated double bonds or molecules with at least each pair of electrons and a double bond. 

    FAQs

    1. Describe Benzene?

    Benzene, with the chemical symbol C6H6, is among the essential organic compounds. The compound of the numerous aromatic compounds is benzene. Benzene is the most foundational organic, aromatic hydrocarbon. Benzene is a basic petrochemical and natural component of crude oil. It is a colourless liquid with an odour of gasoline. In nature, benzene is toxic and carcinogenic. Its primary application is in the manufacture of polystyrene. Although benzene is a naturally occurring element generated by volcanism and forest fires and found in many plants and animals, it also is a large industrial chemical derived from coal and oil. Benzene, as a natural chemical, is a transparent, colourless fluid. Aromatic hydrocarbons are the most significant compound in the organic industry.

    2. What is the effect of delocalization?

    The delocalization effect was experimental tests determined by monitoring the heat of creation of double carbon-carbon- carbon and carbon compound alone or comparing it to the heat of creation of the compound’s total number of double bonds. These measurements show that the entire molecule’s formation temperature is less than the sum of the heat of creation of its constituting double bonds measured separately. This means the molecules will be in a hybrid resonant frequency state with lower power than an individual resonance structure. They are, in other words, more stable. Because of this relationship between delocalization and resonance effect, aromatics are especially stable.

    3. What are the basic principles of resonance?

    Not every resonant structure is equally important to the compound. A few principles are involved that can assist in determining the significance of a resonance structure. The least charged rule states that the resonant structure with the lowest total control is the most substantial.

    The octet principle states that resonance forms with a complete octet are more substantial than those without a complete outer shell. There are two types of resonance:

    Positive charge stabilisation: The most significant forms are those in which positive charges act upon that least electronegative atom.

    Negative charge stabilisation: The most effective forms are those in which negative charges act on most electronegative atoms.

    Covalent bonds: The resonance structure with more covalent bonds is the most significant.

    4. Describe the steps to draw Resonance Structure. 

    Draw the molecule’s Lewis structure- A Structural formula is a simple example of a molecule. It depicts the bonding of atoms as well as their valence states. Begin by writing down the chemical symbol for each element. A single bond is represented by a line linking the two bound atoms. Double bonds are characterised by two lines, while triple bonds are depicted by three. Dots next to the atom represent valence electrons.

    • Recognize the bonds which can change to establish resonant structures- Particles with resonant structures exist inside a hybrid state between the various structures formed by bond variations. While it is difficult to draw the numerous Lewis structures as separate materials, this is only a graphical representation. Charged particles that shape dual bonds can swap between atoms, slightly altering the structure. This type of bond is called “delocalized” because it is evenly distributed across all of the atomic nuclei in the compound. O3 has resonant frequency structures, for example. The double bond can exist between first and second oxygen atoms or between second and third oxygen atoms.

    5. What is the Resonance structure of nitrobenzene?

    Because of an electron-withdrawing group with a double bond adjacent to the phenyl ring of nitrobenzene, the electron in the phenyl ring of nitrobenzene is less than that of benzene. As a result, the phenyl ring of nitrobenzene is much less nucleophilic than that of benzene. The ortho and para postures are positive based on the resonance structures. As a result, in an electrophilic aromatic substitution reaction, the electrophile would react at the meta position rather than at these positions. As a result, if a double bond is conjugated to the phenyl electrophilic aromatic substitution product, it will become the hydra substituted product.

    6. Is it possible to draw resonance structures for ozone?

    Ozone does have two significant resonance structures which contribute to the molecule’s overall hybrid structure. The ozone molecule has 18 valence electrons, with 6 electron densities from each atom. The two Lewis structures for ozone can be drawn. Both structures provide 18 valence electrons: 6 from three bonds and 12 from lone pairs of electrons placed on the oxygens. The two structures are equal in terms of stability, as each has advantages and disadvantages in the formal charge of two oxygens. Consequently, all these structures would then make contributions to the molecule’s overall hybrid structure. Thus it is possible to draw the Resonance structure of ozone.

    Tags: Board ExamsCBSE Class 11Class 11 Chemistry
    Previous Post

    How to Score Good Marks in Science Class 10 CBSE 2022?

    Next Post

    How to Prepare for Physical Chemistry for JEE 2022?

    Next Post
    Physical Chemistry

    How to Prepare for Physical Chemistry for JEE 2022?

    Leave a Reply Cancel reply

    Your email address will not be published. Required fields are marked *

    Contact form

      Talk to our expert



      Resend OTP

      By submitting up, I agree to receive all the Whatsapp communication on my registered number and Aakash terms and conditions and privacy policy

      Recommended

      Republic Day Essay & Speech Ideas

      Republic Day 2023: Importance, Theme & Speech Ideas for Students in English

      Jan 25, 2023, 5:06 PM IST

      JEE Main 2023 Answer Key & Solutions, Complete Steps to Calculate Your Score

      Jan 24, 2023, 1:41 PM IST

      Trending

      JEE Main 2022 Marks vs Rank vs Percentile

      JEE Main Marks vs Rank vs Percentile

      Jan 25, 2023, 1:34 PM IST
      Top 10 Famous Indian Mathematicians and Their Inventions

      Top 10 Indian Mathematicians & Their Inventions

      Jan 26, 2023, 1:30 PM IST

      Popular

      ANTHE'19 DPT

      I registered for ANTHE 2019. How to access the Daily Practice Tests (DPT)?

      Jun 2, 2020, 12:11 PM IST
      This National Level Scholarship Exam offering upto 90% Scholarship for Students in VIII, IX & X Grades

      This National Level Scholarship Exam offering upto 90% Scholarship for Students in VIII, IX & X Grades

      Sep 2, 2022, 6:14 PM IST
      Aakash National Talent Hunt Exam 2018 – A Perfect Start

      Aakash National Talent Hunt Exam 2018 – A Perfect Start

      Jun 2, 2020, 1:10 PM IST
      COVID-19

      The Unsung Heroes of the COVID-19 Pandemic

      Jun 25, 2020, 1:02 PM IST

      Popular Web Stories

    • Documents Required for Medical Admission

    • Dilute vs Concentrated Solution

    • ANTHE Scholarship 2022

    • Destruction of Colloids

    • ANTHE Books

    • Top Medical Colleges in UP

    • Non Biodegradable Items

    • Sum of Circumference of Circles

    • Dithecous Anther

    • Isomers with Molecular Formula c5h12
    • Recent Posts

      • Republic Day 2023: Importance, Theme & Speech Ideas for Students in English
      • JEE Main 2023 Answer Key & Solutions, Complete Steps to Calculate Your Score
      • JEE Main 2023 Session 1 Exams Begin Today, Detailed Paper Analysis to be Out Soon
      • JEE Main 2023 Exam Day Guidelines and Instructions
      • JEE Main Normalisation: How JEE Main NTA Score is Calculated?

      Follow Us

      • NCERT Solutions for Class 6
      • NCERT Solutions for Class 7
      • NCERT Solutions for Class 8
      • NCERT Solutions for Class 9
      • NCERT Solutions for Class 10
      • NCERT Solutions for Class 11
      • NCERT Solutions for Class 12
      • NCERT Solutions
      • Other Text Book Solutions
      • Important Concepts
      • Ask And Answer
      • Aakash Answers

      Copyright © Aakash Institute

      No Result
      View All Result
      • Aakash Home
      • MEDICAL
      • ENGINEERING
      • FOUNDATIONS
      • TOPPERS SPEAK
      • Exam
        • NEET
          • NEET 2023 Eligibility Criteria
          • NEET 2023 Dates
          • NEET 2023 Exam Pattern
          • NEET 2023 Syllabus
          • NEET 2023 Application
          • NEET 2023 Admit Card
          • NEET UG 2023 Result
          • NEET 2023 Cut Off
          • NEET 2023 FAQ
        • JEE Main
          • JEE Main 2023 Eligibility Criteria
          • JEE Main 2023 Dates
          • JEE Main 2023 Exam Pattern
          • JEE Main 2023 Syllabus
          • JEE Main 2023 Application
          • JEE Main 2023 Admit Card
          • JEE Main 2023 Counselling
        • JEE Advanced
          • JEE Advanced 2023 Eligibility Criteria
          • JEE Advanced 2023 Dates
          • JEE Advanced 2023 Application
          • JEE Advanced 2023 Syllabus
          • JEE Advanced 2023 Maths Syllabus
          • JEE Advanced 2023 Physics Syllabus
          • JEE Advanced 2023 Chemistry Syllabus
      • NCERT Solutions
      • NEET PG
        • INI CET

      Copyright © Aakash Institute

      Welcome Back!

      Login to your account below

      Forgotten Password?

      Retrieve your password

      Please enter your username or email address to reset your password.

      Log In