Call Now
1800-102-2727Do you know that an adult blue whale weighs around 2,00,000 kg? How about the weight of the sun? The estimated weight is around 2*1030kg. How about the weight of an ant? They weigh close to 10-4kg.
Now if you observe these numerical values, what strikes out the most is that the magnitude difference is quite huge. So what would be the desired outcome if we want to find and measure the weight of an atom? We could use the existing metric system but the practicality of using those measurements will be rendered useless owing to the very small weight of an atom.
So what do you think should be done in order to overcome this problem?
That's right. Develop a system which accounts for such small values.
In the same line of thinking, it was John Dalton who first suggested a means of expressing relative atomic mass (the measurement term) in 1803. He proposed the use of hydrogen-1 (protium). In short mass of the proton is regarded as the basic unit of mass. So, the simplest unit of mass (mass of a proton) is considered an atomic mass unit (amu or ‘u’).
1 amu = 1.66 10-24 g
Table of contents
Relative atomic mass =
Relative atomic mass = =total number of nucleons
Relative atomic mass = total number of nucleon
Note: Relative atomic mass is unitless.
Mass of 1 atom and expressed in ‘amu’ or ‘u’
Mass of one atom = Mass of total proton + mass of total neutron + mass of total electron
During the calculation of atomic mass (mass of one atom) we neglect the mass of the electron and for numerical simplicity we consider the mass of one proton is equal to the mass of one neutron.
We can say, Mass of a proton = mass of a neutron = mass of a nucleon
Mass of one atom = Mass of total protons + mass of total neutrons = mass of total nucleons
Mass of one atom = total number of nucleons mass of one nucleon
(total number of nucleon = sum of the number of neutrons and protons)
Mass of one atom = total number of nucleons 1.6610-24g
Mass of one atom = total number of nucleon amu
Mass of one atom = R.A.M amu
Atomic mass = R.A.M amu
Example. Calculate the atomic mass of N14 atom
A. 14 amu
B. 14
C. 14 g
D. All of these
Answer: (A)
number of proton = 7
Number of neutron = 14 - 7 = 7
Total number of nucleons = 14
Atomic mass of N atom = 14 amu
Atomic mass unit
Atomic mass of an atom expressed in grams is called gram atomic mass or simply we can say, the mass of 6.022 1023 atoms (Avagadro’s Number) is the gram atomic mass.
Example. Calculate gram atomic mass of N14 atom.
A. 14 amu
B. 14 kg
C. 14 g
D. All of these
Answer: (C)
Solution: we know, the atomic mass of N atom = 14 amu
Note:
Element |
R.A.M |
Atomic mass |
Gram atomic mass |
H |
1 |
1 amu |
1 g |
C |
12 |
12 amu |
12 g |
N |
14 |
14 amu |
14 g |
O |
16 |
16 amu |
16 g |
Ne |
20 |
20 amu |
20 g |
Na |
23 |
23 amu |
23 g |
Mass of 6.022 1023 entities of any particles are considered as the molar mass of that particular substance
.
Simply put mass of one molecule is called molecular mass.
Example. Calculate the molecular mass of water (H2O)
A. 18
B. 18 amu
C. 18 g
D. All of these
Answer: (B)
Molecule |
Molecular mass |
O2 |
32 amu |
H2SO4 |
98 amu |
HCl |
36 amu |
Mass of 1 molecule expressed in grams or mass of 6.022 1023 molecules.
Example. . Calculate gram molecular mass of water (H2O)
A. 18
B. 18 amu
C. 18 g
D. All of these
Answer: (C)
Molecule |
Gram Molecular mass |
O2 |
32 g |
H2SO4 |
98 g |
HCl |
36 g |
It is defined as the total number of atoms present in one molecule is called its atomicity.
E.g- Potassium Permanganate (KMnO4) has 1 atom of potassium + 1 atom of Manganese + 4 atoms of oxygen.
So, atomicity = 6
Molecules |
Atomicity |
H2SO4 |
7 |
HCl |
2 |
H2 |
2 |
Na2CO3.10H2O |
36 |
Q1. Calculate the molecular mass of O3
A. 48
B. 48 amu
C. 48 g
D. All of these
Answer: (B)
Q2. Calculate the relative molecular mass of CO2
A. 44
B. 44 amu
C. 44 g
D. All of these
Answer: (A)
Q3. Calculate the molecular mass of NH3
A. 17
B. 17 amu
C. 17 g
D. All of these
Answer: (C)
Q4. Find atomicity of CuSO4.5H2O
A. 7
B. 10
C. 17
D. 21
Answer: (D)
Question 1. Can relative atomic mass be defined in respect of other elements than carbon?
Answer: yes, mathematically we define relative atomic mass with respect to any other element but according to the scientific community carbon is taken as standard.
Standard definition; Relative atomic mass =
In respect of oxygen; Relative atomic mass =
Question 2. What is the difference between atomic weight and atomic mass?
Answer: Atomic mass is generally used for single isotopes but atomic weight is generally the weighted average of isotopic abundance in nature. Atomic mass is always a whole number because it has a relation with the number of protons and neutrons in the nucleus.
Question 3. Can relative atomic mass of any element be a fraction?
Answer: No, relative atomic mass can never be fractions because it is simply the total number of protons and nucleons. Protons and neutrons are never present in fractions.
Question 4. If relative atomic mass can not be a fraction why somewhere is fractional atomic mass or molar mass mentioned, e.g- Cl35.5
Answer: Cl35.5 written because of its isotopes, Cl present in nature in different isotopes in different natural abundance (%). So, due to their isotopes, they have fractional mass. We can call it weighted average atomic mass.
Average atomic mass |
Mole |
Percentage composition |
Normality |
Strength of solution |
Density |